Naked (CMe)M Cations (M = Sc, Ti, and V) and Their Fluoroarene Complexes.

The ionic metallocene complexes [CpM][BPh] (Cp = CMe) of the trivalent 3d metals Sc, Ti, and V were synthesized and structurally characterized. For M = Sc, the anion interacts weakly with the metal center through one of the phenyl groups, but for M = Ti and V, the cations are naked. They each contai...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 127; no. 41; pp. 14310 - 14320
Main Authors:	Bouwkamp, Marco W., Budzelaar, Peter H. M., Gercama, Jeroen, Morales, Isabel Del Hierro, Wolf, Jeanette De, Meetsma, Auke, Troyanov, Sergei I., Teuben, Jan H., Hessen, Bart
Format:	Article
Published:	American Chemical Society 10/19/2005
Subjects:	Metallocenes Organometallic compounds Organic compounds Cations Tetrahydrofuran Metals
Online Access:	View this record in EBSCOhost