An Electrochemical Color-Switchable RGB Dye: Tristable [2]Catenane.
The article validates using first principle calculations that a tristable [2]- catenane with tetrathiafulvalene and 1,5-dioxynaphthalene units for green and red colors, respectively, as well as a third donor unit, namely a substituted benzidine suitable for generating a blue color, could be the pixe...
| Publicado en: | Journal of the American Chemical Society Vol. 127; no. 46; pp. 15994 - 15996 |
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| Autores principales: | , , , |
| Formato: | Artículo |
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American Chemical Society
11/23/2005
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=19296847&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 19296847 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 11/23/2005 vid: 127 iid: 46 pid: 997 pub: American Chemical Society artinfo: ui: 19296847 10.1021/ja0431298 ppf: 15994 ppct: 2 formats: tig: atl: An Electrochemical Color-Switchable RGB Dye: Tristable [2]Catenane. aug: au: Wei-Qiao Deng Flood, Amar H. Stoddart, J. Fraser Goddard, III, William A. affil: Materials and Process Simulation Center, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena. California 91125. California NanoSvstems Institute and Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095. su: Catenanes Optoelectronic device design & construction Density functionals Molecular orbitals Colors Electric potential sug: subj: Catenanes Optoelectronic device design & construction Density functionals Molecular orbitals Colors Electric potential ab: The article validates using first principle calculations that a tristable [2]- catenane with tetrathiafulvalene and 1,5-dioxynaphthalene units for green and red colors, respectively, as well as a third donor unit, namely a substituted benzidine suitable for generating a blue color, could be the pixel-layer component for the implementation of an electronic paper display. It also proposes a mechanism of switching in the tristable [2]catenane working under different voltages. It determines an empirical scaling factor to correct the band gap calculated from density functional theory by comparing calculated with available experimental values and then uses this factor to predict the unknown absorption maxima. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2005 holdings: @attributes: islocal: N |
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