Very Large Swelling in Hybrid Frameworks: A Combined Computational and Powder Diffraction Study.

Using a combination of simulations and powder diffraction, we report here the study of the very large swelling of a three-dimensional nanoporous iron(lll) carboxylate (MIL-88) which exhibits almost a reversible doubling (∼85%) of its cell volume while fully retaining its open-framework topology. The...

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Publicado en:	Journal of the American Chemical Society Vol. 127; no. 46; pp. 16273 - 16279
Autores principales:	Mellot-Draznieks, Caroline, Serre, Christian, Surblé, Suzy, Audebrand, Nathalie, Fërey, Gérard
Formato:	Artículo
Publicado:	American Chemical Society 11/23/2005
Materias:	Optical diffraction Iron Adsorption (Chemistry) Porous materials Alcohol Water
Acceso en línea:	Ver este registro en EBSCOhost