Mechanism of NO Reduction by the μ-S Tetranuclear Cu Cluster of Nitrous Oxide Reductase.

Reaction thermodynamics and potential energy surfaces are calculated using density functional theory to investigate the mechanism of the reductive cleavage of the N-O bond by the μ-sulfide-bridged tetranuclear Cu site of nitrous oxide reductase. The Cu cluster provides an exogenous ligand-binding si...

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Publicado en:	Journal of the American Chemical Society Vol. 128; no. 1; pp. 278 - 291
Autores principales:	Goreisky, Serge I., Ghosh, Somdatta, Solomon, Edward I.
Formato:	Artículo
Publicado:	American Chemical Society 1/11/2006
Materias:	Nitrous oxide Enzymes Density functionals Catalysis Ligands (Chemistry) Protons
Acceso en línea:	Ver este registro en EBSCOhost