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A Structural Investigation of the N--B Interaction in an o-(N,N-Dialkylaminomethyl)arylboronate System.

o-(Pyrrolidinylmethyl)phenylboronic acid (4) and its complexes with bifunctional substrates such as catechol, α-hydroxyisobutyric acid, and hydrobenzoin have been studied in detail by X-ray crystallography, B NMR, and computational analysis. The N–B interactions in analogous boronic acids and esters...

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Published in:Journal of the American Chemical Society Vol. 128; no. 4; pp. 1222 - 1233
Main Authors: Lei Zhu, Shabbir, Shagufta H., Gray, Mark, Lynch, Vincent M., Sorey, Steven, Anslyn, Eric V.
Format: Article
Published: American Chemical Society 2/1/2006
Subjects:
Catechol
X-ray crystallography
Organic compounds
Chlorohydrocarbons
Trihalomethanes
Structural optimization
Online Access:View this record in EBSCOhost