Hydrogen and Deuterium Atoms in OctasiIsesquioxanes: Experimental and Computational Studies.

The rate of detrapping of atomic hydrogen from several octasilsesquioxanes is the same for dissolved and solid samples and is independent of the presence of other species such as free radicals or oxygen; varying the cage substituents leads to only minor differences in the activation parameters. Hydr...

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Detalles Bibliográficos
Publicado en:Journal of the American Chemical Society Vol. 128; no. 18; pp. 6111 - 6126
Autores principales: Päch, Michael, Macrae, Roderick M., Carmichael, Ian
Formato: Artículo
Publicado: American Chemical Society 5/10/2006
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Acceso en línea:Ver este registro en EBSCOhost