Stepwise Cope Rearrangement of Cyclo-biphenalenyl via an Unusual Multicenter Covalent π-Bonded Intermediate.

Abstract: Multicenter covalent a-bonding between ar-conjugated radicals has been recently recognized as a novel and important bonding interaction. The Cope rearrangement of cyclo-biphenalenyl 9 is studied by exploring its potential energy surface with density functional theory (DFT), and it is found...

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Publicado en:	Journal of the American Chemical Society Vol. 128; no. 22; pp. 7277 - 7287
Autores principales:	Jingsong Huang, Kertesz, Mikios
Formato:	Artículo
Publicado:	American Chemical Society 6/7/2006
Materias:	Cyclic compounds Radicals (Chemistry) Density functionals Chemical bonds Cyclophanes Paramagnetism
Acceso en línea:	Ver este registro en EBSCOhost