Synthesis and Structural Characterization of 1 -Mesityl-1 ,3-dihydro-imidazole-2-selone and Bis(1-mesitylimidazol-2-yl)diselenide: Experimental Evidence That the Selone Is More Stable Than the Selenol Tautomer.
1-Mesityl-1,3-dihydro-imidazole-2-selone, (seim)H, may be obtained from 1-mesitylimidazole via (i) deprotonation with BuLi, (ii) treatment with elemental selenium, and (iii) addition of HCl(aq). Structural characterization of (seim)H by X-ray diffraction demonstrates that the compound exists as the...
| Publicado en: | Journal of the American Chemical Society Vol. 128; no. 38; pp. 12490 - 12498 |
|---|---|
| Autores principales: | , , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
9/27/2006
|
| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |