Neutral and Zwitterion ic Low-Coordinate Titani urn Complexes Bearing the Terminal Phosphinidene Functionality. Structural, Spectroscopic, Theoretical, and Catalytic Studies Addressing the Ti—P Multiple Bond.

α-Hydrogen abstraction and α-hydrogen migration reactions yield novel titanium(IV) complexes bearing terminal phosphinidene ligands. Via an α-H migration reaction, the phosphinidene (nacnac)TiP[Trip](CHBu) (nacnac = [Ar]NC(Bu)CHC(Bu)N[Ar], Ar = 2,6-(CHMe)CH, Trip = 2,4,6-PrCH) was prepared by the a...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 128; no. 41; pp. 13575 - 13586
Main Authors:	Guangyu Zhao, Basuli, Falguni, Kilgore, Uriah J., Fan, Hongiun, Aneetha, Halikhedkar, Huffman, John C., Gang Wu, Mindiola, Daniel J.
Format:	Article
Published:	American Chemical Society 10/18/2006
Subjects:	Titanium compounds Phosphorus compounds Complex compounds Ligands (Chemistry) Chemical structure Catalysis Chemical bonds
Online Access:	View this record in EBSCOhost