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Highly Active Copper-Based Catalyst for Atom Transfer Radical Polymerization.

Atom transfer radical polymerization (ATRP) generally requires a catalyst/initiator molar ratio of 0.1 to 1 and catalyst/monomer molar ratio of 0.001 to 0.01 (i.e., catalyst concentration: 1000–10 000 ppm versus monomer). Herein, we report a new copper-based complex CuBr/N,N,W,N'-tetrakis(2-pyridylm...

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Publicado en:Journal of the American Chemical Society Vol. 128; no. 50; pp. 16277 - 16286
Autores principales: Huadong Tang, Arulsamy, Navamoney, Radosz, Maciej, Shen, Youqing, Tsarevsky, Nicolay V., Braunecker, Wade A., Wei Tang, Matyjaszewski, Krzysztof
Formato: Artículo
Publicado: American Chemical Society 12/20/2006
Materias:
Copper
Polymerization
Monomers
Molecular weights
X-rays
Optical diffraction
Acceso en línea:Ver este registro en EBSCOhost