trans-W(Cmesityl)(dmpe)H: Revealing a Highly Polar W-H Bond and H-Mobility in Liquid and Solid State.

The isotopomeric complexes trans-W(Cmesityl)[(C(H,D))PCHCHP(C(H,D))](H,D) 1-4 were prepared. 2 (W(C)(dmpe)D) was used to study the Deuterium Quadrupole Coupling Constant (DQCC) and the ionicity of the W-D bond (DQCC = 34.1 kHz; ionicity 85%). 1 (W(C)(dmpe)H) shows several dynamic exchange processes...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 129; no. 22; pp. 7195 - 7206
Autores principales:	Fenglou Zou, Furno, Franck, Fox, Thomas, Schmalle, Helmut W., Berke, Heinz, Eckert, Jurgen, Chowdhury, Zema, Burger, Peter
Formato:	Artículo
Publicado:	American Chemical Society 6/6/2007
Materias:	Deuterium Optical diffraction Isomerization Neutrons Scattering (Physics)
Acceso en línea:	Ver este registro en EBSCOhost