Intermolecular C—H Bond Activation Reactions Promoted by Transient Titanium Alkylidynes. Synthesis, Reactivity, Kinetic, and Theoretical Studies of the Ti~C Linkage.

The neopentylidene-neopentyl complex (PNP)TiCHBu(CHBu) (2; PNP = N[2-P(CHMe)-4-methylphenyl]), prepared from the precursor (PNP)TiCHBu(OTf) (1) and LiCHBu, extrudes neopentane in neat benzene under mild conditions (25 °C) to generate the transient titanium alkylidyne, (PNP)TiCBu (A), which subseq...

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Publicado en:	Journal of the American Chemical Society Vol. 129; no. 28; pp. 8781 - 8794
Autores principales:	Bailey, Brad C., Hongjun Fan, Huffman, John C., Mu-Hyun Baik, Mindiola, Daniel J.
Formato:	Artículo
Publicado:	American Chemical Society 7/18/2007
Materias:	Chemical bonds Chemical structure Physical & theoretical chemistry Titanium compounds Chlorodimethylpropane
Acceso en línea:	Ver este registro en EBSCOhost