Design of All-Inorganic Molecular-Based Photocatalysts Sensitive to Visible Light: Ti(IV)—O—Ce(III) Bimetallic Assemblies on Mesoporous Silica.
The article reports on the first photocatalysis driven by the visible-light induced metal-to-metal charge transfer (MMCT) for hetero-bimettalic Ti(IV)-O—Ce(III) assemblies on the pore of mesoporous silica. The combination of Ti(IV) and Ce(III) enabled to drive the photocatalytic oxidative decomposit...
| Published in: | Journal of the American Chemical Society Vol. 129; no. 31; pp. 9596 - 9598 |
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| Main Authors: | , , , , |
| Format: | Article |
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American Chemical Society
8/8/2007
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| Subjects: | |
| Online Access: | View this record in EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=26373010&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 26373010 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 8/8/2007 vid: 129 iid: 31 pid: 997 pub: American Chemical Society artinfo: ui: 26373010 10.1021/ja073668n ppf: 9596 ppct: 2 formats: tig: atl: Design of All-Inorganic Molecular-Based Photocatalysts Sensitive to Visible Light: Ti(IV)—O—Ce(III) Bimetallic Assemblies on Mesoporous Silica. aug: au: Nakamura, Ryuhei Okamoto, Akihiro Osawa, Hitoshi Irie, Hiroshi Hashimoto, Kazuhito affil: Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan Japan Synchrotron Radiation Research Institute, 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan Exploratory Research for Advanced Technology (ERATO), JST su: Photocatalysis Charge transfer Ion exchange (Chemistry) Titanium Acetone Carbon dioxide Irradiation sug: subj: Photocatalysis Charge transfer Ion exchange (Chemistry) Titanium Acetone Carbon dioxide Irradiation ab: The article reports on the first photocatalysis driven by the visible-light induced metal-to-metal charge transfer (MMCT) for hetero-bimettalic Ti(IV)-O—Ce(III) assemblies on the pore of mesoporous silica. The combination of Ti(IV) and Ce(III) enabled to drive the photocatalytic oxidative decomposition of 2-propanol into acetone and carbon dioxide under visible-light irradiation. Results of the study and its implications are presented and discussed. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2007 holdings: @attributes: islocal: N |
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