Gas-Phase Synthesis of the Homo and Hetero Organocuprate Anions [MeCuMe], [EtCuEt], and [MeCuR].

The homocuprates [MeCuMe] and [EtCuEt] were generated in the gas phase by double decarboxylation of the copper carboxylate centers [MeCOCuOCMe] and [EtCOCuOCEt], respectively. The same strategy was explored for generating the heterocuprates [MeCuR] from [MeCOCuOCR] (R = Et, Pr, iPr, tBu, allyl, benz...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 3; pp. 1069 - 1080
Autores principales:	Rijs, Nicole, Khairallah, George N., Waters, Tom, Ohair, Richard A. J.
Formato:	Artículo
Publicado:	American Chemical Society 1/23/2008
Materias:	Chemical research Physical & theoretical chemistry Hydrogen-ion concentration Mass spectrometry Density functionals
Acceso en línea:	Ver este registro en EBSCOhost