Structural and Spectroscopic Characterization of Mononuclear Copper(l) Nitrosyl Complexes: End-on versus Side-on Coordination of NO to Copper(l).

Two crystal structures of the mononuclear copper(l)-nitrosyl complexes [Cu(L3)(NO)] (1) and [Cu(L3′)(NO)](ClO) (2) with the related coligands L3 (hydrotris(3-tert-butyl-5-isopropyl-1 -pyrazolyl)borate) and L3′ (tris(3-tert-butyl-5-isopropyl-1-pyrazolyl)methane) are presented. These compounds are the...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 130; no. 4; pp. 1205 - 1214
Main Authors:	Fujisawa, Kiyoshi, Tateda, Akira, Miyashita, Yoshitaro, Okamoto, Ken-Ichi, Paulat, Florian, Praneeth, V. K. K., Merkle, Anna, Lehnert, Nicolai
Format:	Article
Published:	American Chemical Society 1/30/2008
Subjects:	Mononucleosis Molecular spectroscopy Electronic structure Density functionals Electronic systems Electronic circuit design
Online Access:	View this record in EBSCOhost