Pressure-Induced Polymerization of Diiodobutadiyne in Assembled Cocrystals.

Diiodobutadiyne forms cocrystals with bis(pyridyl)oxalamides in which the diyne alignment is near the ideal parameters for topochemical polymerization to the ordered conjugated polymer, poly-(diiododiacetylene) (PIDA). Nonetheless, previous efforts to induce polymerization in these samples via heat...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 13; pp. 4415 - 4421
Autores principales:	Wilhelm, Christopher, Boyd, Stephen A., Chawda, Samrat, Fowler, Frank W., Goroff, Nancy S., Halada, Gary P., Grey, Clare P., Lauher, Joseph W., Liang Luo, Martin, C. David, Parise, John B., Tarabrella, Cathy, Webb, Jeffrey A.
Formato:	Artículo
Publicado:	American Chemical Society 4/2/2008
Materias:	Polymerization Crystals Polymers Optical diffraction Chemical reactions
Acceso en línea:	Ver este registro en EBSCOhost