The Mechanism of the Rhodium(I)-Catalyzed [2 + 2 + 1] Carbocyclization Reaction of Dienes and CO: A Computational Study.

The rhodium(I) catalyzed [2 + 2 + 1] carbocyclization of tethered diene-enes to afford substituted hexahydropentalenones with high levels of diastereoselectivity was modeled using density functional theory. Previously, this transformation was observed to be facile, whereas the analogous bis-ene subs...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 17; pp. 5821 - 5831
Autores principales:	Pitcock Jr., William H., Lord, Richard L., Mu-Hyun Baik
Formato:	Artículo
Publicado:	American Chemical Society 4/30/2008
Materias:	Rhodium Density functionals Electron distribution Chemical reactions Chemistry education
Acceso en línea:	Ver este registro en EBSCOhost