Correlating the Crystal Structure of A Thiol-Protected Au Cluster and Optical Properties.

The article focuses on the unusual single crystal structure of a phenylethanethiol-capped, 25-atom gold cluster. Researchers correlated the structure with its optical absorption spectrum by performing time-dependent density functional theory (TDDFT) calculations. They suggested the importance to pre...

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Publicado en:Journal of the American Chemical Society Vol. 130; no. 18; pp. 5883 - 5886
Autores principales: Manzhou Zhu, Aikens, Christine M., Hollander, Frederick J., Schatz, George C., Jin, Rongchao
Formato: Artículo
Publicado: American Chemical Society 5/7/2008
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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        atl: Correlating the Crystal Structure of A Thiol-Protected Au Cluster and Optical Properties.
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          Manzhou Zhu
          Aikens, Christine M.
          Hollander, Frederick J.
          Schatz, George C.
          Jin, Rongchao
        affil:
          Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvannia 15213
          Department of Chemistry, Kansas State University, Manhattan, Kansas 66506
          College of Chemistry, University of California at Berkeley, Berkeley, California 94720
          Department of Chemistry, Northwestern University, Evanston, Illinois 60208
      su:
        Crystal field theory
        Cluster analysis (Statistics)
        Density functionals
        Functional analysis
        Gold
      sug:
        subj:
          Crystal field theory
          Cluster analysis (Statistics)
          Density functionals
          Functional analysis
          Gold
      ab: The article focuses on the unusual single crystal structure of a phenylethanethiol-capped, 25-atom gold cluster. Researchers correlated the structure with its optical absorption spectrum by performing time-dependent density functional theory (TDDFT) calculations. They suggested the importance to prepare a series of size discrete gold thiolate clusters and to characterize their structures within the range.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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