Palladium Vacataporphyrin Reveals Conformational Rearrangements Involving Hückel and Möbius Macrocyclic Topologies.

5,10,15,20-Tetraaryl-21-vacataporphyrin (butadieneporphyrin, an annulene-porphyrin hybrid) which contains a vacant space instead of heteroatomic bridge acts as a ligand toward palladium(II). The metal ion of square-planar coordination geometry is firmly held via three pyrrolic nitrogen atoms where t...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 19; pp. 6182 - 6196
Autores principales:	Pacholska-Dudziak, Ewa, Skonieczny, Janusz, Pawlicki, Miłosz, Szterenberg, Ludmiła, Ciunik, Zbigniew, Latos-Grażyński, Lechosław
Formato:	Artículo
Publicado:	American Chemical Society 5/14/2008
Materias:	Physical & theoretical chemistry research Palladium Conformational analysis Macrocyclic compounds Nuclear magnetic resonance Density functionals
Acceso en línea:	Ver este registro en EBSCOhost