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H Storage Materials (22KJ/mol) Using Organometallic Ti Fragments as σ-H2 Binding Sites.

Low-coordinate Ti (III) fragments with controlled geometries designed specifically for σ-H binding were grafted onto mesoporous silica using tri- and tetrabenzyl Ti precursors. The hydrogen storage capacity was tested as a function of precursor and precursor loading level. At an optimal loading leve...

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Published in:Journal of the American Chemical Society Vol. 130; no. 22; pp. 6992 - 7000
Main Authors: Hamaed, Ahmad, Trudeau, Michet, Antonelli, David M.
Format: Article
Published: American Chemical Society 6/4/2008
Subjects:
Organometallic compounds
Titanium compounds
Hydrogen
Adsorption (Chemistry)
Chemistry
Online Access:View this record in EBSCOhost