On the Origin of Alternating Bond Distortions and the Emergence of Chirality in Polyoxometalate Anions.

Alternating short and long bond length (ABL) distortions observed within the ring structures of molecular metal oxide anions or polyoxometalates (POMs) are reminiscent of the cooperative linear ABL distortions in perovskite d; metal oxides. We show herein that these distortions have a common origin:...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 26; pp. 8223 - 8234
Autores principales:	Likai Yan, Lopez, Xavier, Carbó, Jorge J., Sniatynsky, Richard, Duncan, Dean C., Poblet, Josep M.
Formato:	Artículo
Publicado:	American Chemical Society 7/2/2008
Materias:	Metallic oxides Chirality Perovskite Density functionals Quantum chemistry
Acceso en línea:	Ver este registro en EBSCOhost