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Systematic Functionalization of a Metal—Organic Framework via a Postsynthetic Modification Approach.

The pendant amino groups in isoreticular metal-organic framework-3 (IRMOF-3) were subjected to postsynthetic modification with 10 linear alkyl anhydrides (O(CO(CH)CH)2 (where n = 1 to 18) and the extent of conversion, thermal and structural stability, and Brunauer-Emmett-Teller (BET) surface areas o...

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Published in:Journal of the American Chemical Society Vol. 130; no. 26; pp. 8508 - 8518
Main Authors: Tanabe, Kristine K., Zhenqiang Wang, Cohen, Seth M.
Format: Article
Published: American Chemical Society 7/2/2008
Subjects:
Anhydrides
Alkylating agents
Crystals
Optical diffraction
X-rays
Online Access:View this record in EBSCOhost

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