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Noncovalent Interactions under Extreme Conditions: High-Pressure and Low-Temperature Diffraction Studies of the Isostructural Metal - Organic Networks (4-Chloropyridinium)[sub2][CoX[sub4]] (X = Cl, Br).

The crystal structures of the two isostructural metal-organic salts, (4-chloropyridinium)[sub2][CoX[sub4], X = Cl (1), Br (2), have each been determined at nine temperatures from 30 to 300 K and at nine pressures from atmospheric pressure to 4.2 GPa. A 5% reduction in unit cell volume is observed up...

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Published in:Journal of the American Chemical Society Vol. 130; no. 28; pp. 9058 - 9072
Main Authors: Espaliargas, Guillermo Mínguez, Brammer, Lee, Allan, David R., Pulham, Cohn R., Robertson, Neil, Warren, John E.
Format: Article
Published: American Chemical Society 7/16/2008
Subjects:
Optical diffraction
Chemical bonds
Halogen compounds
Hydrogen bonding
Metals at low temperatures
Pressure measurement
Anisotropy
Online Access:View this record in EBSCOhost