Reversible Mechanochromic Luminescence of [(CFAu)(μ-1 ,4-Diisocyanobenzene)].

The article discusses the mechanochromic luminescence behavior of [(CFAu)(µ-1,4 -diisocyanobenzene)]. According to the authors, optical properties, powder X-ray diffraction, infrared measurements and X-ray crystallographic analysis strongly suggest that the mechanochromic property is attributable to...

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Detalles Bibliográficos
Publicado en:Journal of the American Chemical Society Vol. 130; no. 31; pp. 10044 - 10046
Autores principales: Ito, Hajime, Saito, Tomohisa, Oshima, Naoya, Kitamura, Noboru, Ishizaka, Shoji, Hinatsu, Yukio, Wakeshima, Makoto, Kato, Masako, Tsuge, Kiyoshi, Sawamura, Masaya
Formato: Artículo
Publicado: American Chemical Society 8/6/2008
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Acceso en línea:Ver este registro en EBSCOhost
Descripción
Sumario:The article discusses the mechanochromic luminescence behavior of [(CFAu)(µ-1,4 -diisocyanobenzene)]. According to the authors, optical properties, powder X-ray diffraction, infrared measurements and X-ray crystallographic analysis strongly suggest that the mechanochromic property is attributable to changes in the molecular arrangement, rather than molecular structure of the Au complexes in the solid state.