Insight into the Mechanism of the Asymmetric Ring-Opening Aminolysis of 4,4-Dimethyl-3,5,8-trioxabicyclo[5.1.0]octane Catalyzed by Titanium/BI NOLate/Water System: Evidence for the Ti(BINOLate)2-Bearing Active Catalyst Entities and the Role of Water.

The mechanism of the enantioselective ring-opening aminolysis of 4,4-dimethyl-3,5,8- trioxabicyclo[5.1.0]octane with benzylamine, catalyzed by the titanium-BINOLate species generated in situ from a mixture of enantiopure BINOL (1,1′-bi-2-naphthol), Ti(OiPr), and HO in the presence of benzylamine in...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 31; pp. 10116 - 10128
Autores principales:	Hongli Bao, Jing Zhou, Zheng Wang, Ylniong Guo, Tianpa You, Kuiling Ding
Formato:	Artículo
Publicado:	American Chemical Society 8/6/2008
Materias:	Cyclic compounds Catalysis Alkanes Titanium Catalysts Water Ring formation (Chemistry)
Acceso en línea:	Ver este registro en EBSCOhost