Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes.

A series of complexes [Fe[supIV](O)(TMC)(X)+ (where X = 0H, CF[sub3]CO[sub2], N[sub3], NCS, NCO, and CN) were obtained by treatment of the well-characterized nonheme oxoiron(IV) complex [Fe[supIV](O)(TMC)- (NCMe)][sup2+] (TMC = tetramethylcyclam) with the appropriate NR4X salts. Because of the topol...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 37; pp. 12394 - 12408
Autores principales:	Jackson, Timothy A., Rohde, Jan-Uwe, Mi Sook Seo, Sastri, Chivukula V., DeHont, Raymond, Stubna, Audria, Ohta, Takehiro, Kitagawa, Teizo, Münck, Eckard, Nam, Wonwoo, Que Jr., Lawrence
Formato:	Artículo
Publicado:	American Chemical Society 9/17/2008
Materias:	Ligands (Chemistry) Oxygen Iron Density functionals Electronic structure Complex compounds Extended X-ray absorption fine structure
Acceso en línea:	Ver este registro en EBSCOhost