Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis
The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One r...
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Logos Verlag Berlin
2020
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=nlebk&AN=3541181&site=ehost-live header: @attributes: shortDbName: nlebk uiTerm: 3541181 longDbName: eBook Collection (EBSCOhost) uiTag: AN controlInfo: bkinfo: btl: Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis aug: au: Daniel Knoll sertl: Beiträge Zur Organischen Synthese isbn: 9783832550714 imageinfo: pubinfo: dt: @attributes: year: 2020 month: 01 day: 01 dtAvail: @attributes: year: 2023 month: 04 day: 17 pub: Logos Verlag Berlin pubContract: Logos Verlag Berlin GmbH place: Berlin, Germany price: 0.01 limitsGroup: maxCheckoutDays: 1500 pda: N printPagesOffline: 100 printPagesOnline: 100 previewPages: 10000 prePubGroup: dewey: @attributes: class: 547.59 item: 547 .59 lc: @attributes: class: QD400 item: QD 400 artinfo: ui: 3541181 1266753357 formats: fmt: @attributes: type: EB doid: NL$3541181$PDF caption: PDF download: Y tig: atl: Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis ptl: Heterobimetallic [2.2]Paracyclophane Complexes and Their Application in Photoredox Catalysis aug: au: Daniel Knoll su: Cyclophanes Heterocyclic compounds sug: subj: SCIENCE / Chemistry / General SCIENCE / General Cyclophanes Heterocyclic compounds ab: The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. pubtype: eBook doctype: Book ougenre: Book language: English copyright: @attributes: flag: N copyrightText: holdings: @attributes: islocal: N |
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