Theoretical Investigation of Water Exchange on the Nanometer-Sized Polyoxocation AlOAl(OH)(HO) (Keggin-Al) in Aqueous Solution.

The article presents a study on the water exchange on Keggin-Al (K-Al) in aqueous solution by performing supermolecule density functional theory calculations. It states that that the result of the study suggest a dissociative mechanism (D) for the water exchange on K-Al. It mentions that the study o...

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Publicado en:Journal of the American Chemical Society Vol. 130; no. 44; pp. 14402 - 14404
Autores principales: Zhaosheng Qian, Hui Feng, Wenjing Yang, Shuping Bi
Formato: Artículo
Publicado: American Chemical Society 11/5/2008
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 11/5/2008
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        atl: Theoretical Investigation of Water Exchange on the Nanometer-Sized Polyoxocation AlOAl(OH)(HO) (Keggin-Al) in Aqueous Solution.
      aug:
        au:
          Zhaosheng Qian
          Hui Feng
          Wenjing Yang
          Shuping Bi
        affil: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry of China & Key Laboratory of MOE for Life Science, Nanjing University, Nanjing 210093, China
      su:
        Minerals
        Density functionals
        Water transfer
        Water quality
        Functional analysis
      sug:
        subj:
          Minerals
          Density functionals
          Water transfer
          Water quality
          Functional analysis
      ab: The article presents a study on the water exchange on Keggin-Al (K-Al) in aqueous solution by performing supermolecule density functional theory calculations. It states that that the result of the study suggest a dissociative mechanism (D) for the water exchange on K-Al. It mentions that the study offers a mean for exploring the chemical behavior of mineral-water interfaces and dissolution and transformation processes of the minerals.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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