Structural Transformations and Adsorption of Fuel-Related Gases of a Structurally Responsive Nickel Phosphonate Metal--Organic Framework, Ni-STA-12.

The structure of the nickel N,N′-piperazinebismethylenephosphonate, Ni-STA-12 (St. Andrews porous material-12), has been determined in the hydrated (NiL∙8HO, L = OPCHNCHNCHPO), partially dehydrated (NiL∙2HO), and fully dehydrated (NiL) forms from high-resolution synchrotron X-ray powder diffraction....

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 130; no. 47; pp. 15967 - 15982
Main Authors:	Miller, Stuart A., Pearce, Gordon M., Wright, Paul A., Bonino, Francesca, Chavan, Sachin, Bordiga, Silvia, Margiolaki, Irene, Guillou, Nathalie, Férey, Gérard, Bourrelly, Sandrine, Llewellyn, Philip L.
Format:	Article
Published:	American Chemical Society 11/26/2008
Subjects:	Adsorption (Chemistry) Separation (Technology) Surface chemistry Structural frames Spectrum analysis Atmospheric temperature Chemical structure Physical & theoretical chemistry
Online Access:	View this record in EBSCOhost