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Mixed Alkylamido Aluminate as a Kinetically Controlled Base.

The mechanisms by which directed ortho metalation (DoM) and postmetalation processes occur when aromatic compounds are treated with mixed alkylamido aluminate i-BuAI(TMP)Li (TMP-aluminate 1; TMP = 2,2,6,6-tetramethylpiperidide) have been investigated by computation and X-ray diffraction. Sequential...

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Published in:Journal of the American Chemical Society Vol. 130; no. 48; pp. 16193 - 16201
Main Authors: Naka, Hiroshi, Morey, James V., Haywood, Joanna, EisIer, Dana J., McPartIin, Mary, García, Felipe, Kudo, Hironaga, Kondo, Yoshinori, Uchiyama, Masanobu, WheatIey, Andrew E. H.
Format: Article
Published: American Chemical Society 12/3/2008
Subjects:
Aromatic compounds
Aluminates
Aluminum compounds
Chemistry
Optical diffraction
Online Access:View this record in EBSCOhost