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Spectral Diffusion Induced by Proton Dynamics in Pigment—Protein Complexes.

The fluorescence emission of individual photosystem I complexes from Synechocystis PCC 6803 in protonated and deuterated buffer shows zero-phonon lines as well as broad intensity distributions. The number and the line width of the zero phonon lines depend strongly on the solvent (H[sub2]O/D[sub2]O)....

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Published in:Journal of the American Chemical Society Vol. 130; no. 51; pp. 17487 - 17494
Main Authors: Brecht, Marc, Studier, Hauke, Radics, Volker, Nieder, Jana B., Bittl, Robert
Format: Article
Published: American Chemical Society 12/24/2008
Subjects:
Diffusion processes
Buffer solutions
Fluorescence
Phonons
Solvents
Protons
Spectrum analysis
Online Access:View this record in EBSCOhost