Time-Resolved X-ray Scattering of an Electronically Excited State in Solution. Structure of the ³A State of Tetrakis-μ-pyrophosphitodiplatinate(ll).

The structure of the ³A excited state of tetrakis-µ-pyrophosphitodiplatinate(ll) in aqueous solution is investigated by time-resolved X-ray scattering on a time scale from 100 ps to 1 µs after optical pumping. The primary structural parameter, the Pt-Pt distance, is found to be 2.74 Å, which is 0.24...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 131; no. 2; pp. 502 - 509
Main Authors:	Christensen, Morten, Haldrup, Kristofter, Bechgaard, Klaus, Feidenhans, Robert, Qingyu Kong, Cammarata, Marco, Lo Russo, Manuela, Wulff, Michael, Harrit, Niels, Nielsen, Martin Meedom
Format:	Article
Published:	American Chemical Society 1/21/2009
Subjects:	X-ray scattering Excited state chemistry Energy levels (Quantum mechanics) Multiphoton processes Optical diffraction
Online Access:	View this record in EBSCOhost