Tuning the Oxidation Level, the Spin State, and the Degree of Electron Delocalization in Homo- and Heteroleptic Bis(α-diimine)iron Complexes.

The four-coordinate heteroleptic complex [Fe (pda)(Fdad)] (1) and its homoleptic analogue [Fe(dad)] (2), where pda is the closed-shell ligand N,N'-bis(pentafluorophenyl)-o-phenylenedia- mide(2-) and dad is the singly reduced N,N'-bis(pentafluorophenyl)-2,3-dimethyl-1,4-diazabutadiene π-radical anion...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 131; no. 3; pp. 1208 - 1222
Main Authors:	Khusniyarov, Marat M., Weyhermuller, Thomas, Bill, Eckhard, Wieghardt, Karl
Format:	Article
Published:	American Chemical Society 1/28/2009
Subjects:	Oxidation Spectrum analysis X-ray crystallography Density functionals Ligands (Chemistry)
Online Access:	View this record in EBSCOhost