Mössbauer and DFT Study of the Ferromagnetically Coupled Diiron(IV) Precursor to a Complex with an FeO Diamond Core.

Recently, we reported the reaction of the (μ-oxo)diiron(III) complex 1 ([Fe(μ-O)(μ-OH)(L)], L tris(3,5-dimethyl-4-methoxypyridyl-2-methyl)amine) with 1 equiv of HO to yield a diiron(IV) intermediate, 2 (Xue, G.; Fiedler, A. T.; Martinho, M.; Münck, E.; Que, L., Jr. Proc. Natl. Acad. Sci. U.S.A. 2008...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 16; pp. 5823 - 5831
Autores principales:	Martinho, Marlene, Genqiang Xue, Fiedler, Adam T., Que, Jr., Lawrence, Bominaar, Emile L., Münck, Eckard
Formato:	Artículo
Publicado:	American Chemical Society 4/29/2009
Materias:	Ferromagnetic materials Methane Monooxygenases Density functionals Magnetic fields
Acceso en línea:	Ver este registro en EBSCOhost