Hydrogen-Promoted Oxygen Activation by Free Gold Cluster Cations.

Small gas-phase gold cluster cations are essentially inert toward molecular oxygen. Preadsorption of molecular hydrogen, however, is found to cooperatively activate the binding of O to even-size AU (x = 2, 4, 6) clusters. Measured temperature- and reaction-time-dependent ion intensities, obtained by...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 25; pp. 8939 - 8952
Autores principales:	Lang, Sandra M., Bernhardt, Thorsten M., Barnett, Robert N., Bokwon Yoon, Landman, Uzi
Formato:	Artículo
Publicado:	American Chemical Society 7/1/2009
Materias:	Ion traps Density functionals Molecular structure Mass spectrometry Hydrogen analysis Oxygen Charge transfer
Acceso en línea:	Ver este registro en EBSCOhost