Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(ll) Complexes.

The article discusses the complexes of the first carbonare-based pincer ligand family metalated with palladium (Pd). It refers to the density functional theory (DFT) calculations, indicating that the electronic structure of the complex derived from the new ligand is separated from its hydrocarbon an...

Descripción completa

Detalles Bibliográficos
Publicado en:Journal of the American Chemical Society Vol. 131; no. 27; pp. 9482 - 9484
Autores principales: Spokoyny, Alexander M., Reuter, Matthew G., Stern, Charlotte L., Ratner, Mark A., Seideman, Tamar, Mirkin, Chad A.
Formato: Artículo
Publicado: American Chemical Society 7/15/2009
Materias:
Acceso en línea:Ver este registro en EBSCOhost
fields @attributes:
  recordID: 1
pdfLink:
plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=43515598&site=ehost-live
header:
  @attributes:
    shortDbName: hlh
    uiTerm: 43515598
    longDbName: Humanities International Complete
    uiTag: AN
  controlInfo:
    bkinfo:
    jinfo:
      jid:
        00027863
        ACS
      jtl: Journal of the American Chemical Society
      issn: 00027863
      maglogo: N
    pubinfo:
      dt: 7/15/2009
      vid: 131
      iid: 27
      pid: 997
      pub: American Chemical Society
    artinfo:
      ui:
        43515598
        10.1021/ja902526k
      ppf: 9482
      ppct: 2
      formats:
      tig:
        atl: Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(ll) Complexes.
      aug:
        au:
          Spokoyny, Alexander M.
          Reuter, Matthew G.
          Stern, Charlotte L.
          Ratner, Mark A.
          Seideman, Tamar
          Mirkin, Chad A.
        affil: Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208
      su:
        Palladium
        Ligands (Chemistry)
        Density functionals
        Electronic structure
        Hydrocarbons
        Molecular structure
        X-ray diffraction
        Biochemistry
      sug:
        subj:
          Palladium
          Ligands (Chemistry)
          Density functionals
          Electronic structure
          Hydrocarbons
          Molecular structure
          X-ray diffraction
          Biochemistry
      ab: The article discusses the complexes of the first carbonare-based pincer ligand family metalated with palladium (Pd). It refers to the density functional theory (DFT) calculations, indicating that the electronic structure of the complex derived from the new ligand is separated from its hydrocarbon analogues. It defines the solid-state molecular structure of the complex using the single crystal X-ray diffraction methods. Insights from the preliminary DFT calculations are provided.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
    refInfo:
    copyright:
      @attributes:
        flag: Y
      dt:
        @attributes:
          year: 2009
    holdings:
      @attributes:
        islocal: N