Regioselectivity in the Reductive Bond Cleavage of Diarylalkylsulfonium Salts: Variation with Driving Force and Structure of Sulfuranyl Radical Intermediates.

This investigation was stimulated by reports that one-electron reductions of monoaryldialkylsul- fonium salts never give aryl bond cleavage whereas reductions of diarylmonoalkylsulfonium salts preferentially give aryl bond cleavage. We studied the product ratios from the reductive cleavage of di-4-t...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 29; pp. 10015 - 10023
Autores principales:	Kampmeier, Jack A., Hoque, Mansurul, Saeva, Frankhn D., Wedegaertner, Donald K., Thomsen, Pia, UlIah, Salt, Krake, Jacob, Lund, Torben
Formato:	Artículo
Publicado:	American Chemical Society 7/29/2009
Materias:	Chemical reduction Density functionals Chemical structure Electrolysis Radicals (Chemistry) Intermediates (Chemistry) Arylation
Acceso en línea:	Ver este registro en EBSCOhost