Heavier Group 2 Metals and Intermolecular Hydroamination: A Computational and Synthetic Assessment.
The article presents a study which offers a computational and synthetic assessment of heavier group 2 metals and intermolecular hydroamination. The study utilized a density functional theory (DFT) that aims to highlight the intrinsic reaction barriers in the catalytic mechanism. The results of the s...
| Publicado en: | Journal of the American Chemical Society Vol. 131; no. 36; pp. 12906 - 12908 |
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| Autores principales: | , , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
9/16/2009
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=44466037&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 44466037 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 9/16/2009 vid: 131 iid: 36 pid: 997 pub: American Chemical Society artinfo: ui: 44466037 10.1021/ja905615a ppf: 12906 ppct: 2 formats: tig: atl: Heavier Group 2 Metals and Intermolecular Hydroamination: A Computational and Synthetic Assessment. aug: au: Barrett, Anthony G. M. Brinkmann, Christine Crimmin, Mark R. Hill, Michael S. Hunt, Patricia Procopiou, Panayiotis A. affil: Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London SW7 2AZ, U.K. Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, U.K. GlaxoSmithKline Medicines Research Centre, Gunnels Wood Road, Stevenage, Hertfordshire SG1 2NY, U.K. su: Metals Density functionals Functional analysis Catalysis Alkenes Coulomb functions Chemical research Inorganic chemistry sug: subj: Metals Density functionals Functional analysis Catalysis Alkenes Coulomb functions Chemical research Inorganic chemistry ab: The article presents a study which offers a computational and synthetic assessment of heavier group 2 metals and intermolecular hydroamination. The study utilized a density functional theory (DFT) that aims to highlight the intrinsic reaction barriers in the catalytic mechanism. The results of the study support rate-determining alkene insertion that occurred inside a catalytic cycle dominated by Coulomb interactions. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2009 holdings: @attributes: islocal: N |
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