Enhancing the Photochemical Stability of N,C-Chelate Boryl Compounds: C-C Bond Formation versus C=C Bond cis,trans-Isomerization.
N,C-Chelate boron compounds such as B(ppy)Mes (ppy = 2-phenylpyridyl, Mes = mesityl) have been recently shown to undergo a facile and reversible C-C/C-B bond rearrangement upon irradiation with UV-light, quenching the emission of the sample and limiting their use in optoelectronic devices. To addres...
| Publicado en: | Journal of the American Chemical Society Vol. 131; no. 40; pp. 14549 - 14560 |
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| Autores principales: | , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
10/14/2009
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |