Redox-Active Metallomacrocycles and Cyclic Metallopolymers: Photocontrolled Ring-Opening Oligomerization and Polymerization of Silicon-Bridged [1]Ferrocenophanes Using Substitutionally-Labile Lewis Bases as Initiators.

Irradiation of silicon-bridged [1]ferrocenophane [Fe(η-CH)SiMe] (1) in the presence of substitutionally labile Lewis bases such as 4,4'-dimethyl-2,2'-bipyridine (Mebpy) initiates ring-opening polymerization and oligomerization via cleavage of an iron-cyclopentadienyl bond. A distribution of cyclic p...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 41; pp. 14958 - 14969
Autores principales:	Herbert, David E., Gilroy, Joe B., Wing Yan Chan, Chabanne, Laurent, Staubitz, Anne, Lough, Alan J., Manners, Ian
Formato:	Artículo
Publicado:	American Chemical Society 10/21/2009
Materias:	Irradiation Silicon Bipyridine Oligomers Chromatographic analysis
Acceso en línea:	Ver este registro en EBSCOhost