Stabilizing Zr and Ti Cations by Interaction With a Ferrocenyl Fragment.
The article presents a research on the stabilization of zirconium (Zr) and titanium (Ti) cations through interactions with ferrocenyl fragment. It discusses how early metal cations react with ferrocene wherein the carbon-hydrogen (CH)-activation of ferrocene has resulted in stable but active polymer...
| Published in: | Journal of the American Chemical Society Vol. 131; no. 43; pp. 15610 - 15612 |
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| Main Authors: | , , |
| Format: | Article |
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American Chemical Society
11/4/2009
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| Subjects: | |
| Online Access: | View this record in EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=45441734&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 45441734 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 11/4/2009 vid: 131 iid: 43 pid: 997 pub: American Chemical Society artinfo: ui: 45441734 10.1021/ja9077446 ppf: 15610 ppct: 2 formats: tig: atl: Stabilizing Zr and Ti Cations by Interaction With a Ferrocenyl Fragment. aug: au: Ramos, Alberto Otten, Edwin Stephan, Douglas W. affil: Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada, M5S 3H6 su: Cations Transition metal compounds Zirconium Titanium Ferrocene Polymerization Chemical bonds Transition metal catalysts sug: subj: Cations Transition metal compounds Zirconium Titanium Ferrocene Polymerization Chemical bonds Transition metal catalysts ab: The article presents a research on the stabilization of zirconium (Zr) and titanium (Ti) cations through interactions with ferrocenyl fragment. It discusses how early metal cations react with ferrocene wherein the carbon-hydrogen (CH)-activation of ferrocene has resulted in stable but active polymerization catalysts. It shows that electron-rich metal fragments have the ability to stabilize electrophillic ZR cations through combining Iron (Fe) and Zr interactions with agnostic CH bonds. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2009 holdings: @attributes: islocal: N |
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