Single-Ion Reorganization Free Energy of Aqueous Ru(bpy) and Ru(HO) from Photoemission Spectroscopy and Density Functional Molecular Dynamics Simulation.

Photoelectron spectroscopy and density functional molecular dynamics simulations are combined to quantify and characterize the redox properties of Ru(bpy) and Ru(HO) in aqueous solution. We report the energy-resolved photoelectron spectrum of aqueous Ru(bpy) at 200 eV photon energy. From the peak po...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 44; pp. 16127 - 16138
Autores principales:	Seidel, Robert, Faubel, Manfred, Winter, Bernd, Blumberger, Jochen
Formato:	Artículo
Publicado:	American Chemical Society 11/11/2009
Materias:	Linear free energy relationship Conditions & laws of chemical reaction Photoemission Spectrum analysis Molecular dynamics Chemical research
Acceso en línea:	Ver este registro en EBSCOhost