Selective Lithiation and Phosphane-Functionalization of [(η-CH)Ti(η-CH)] (Troticene) and Its Use for the Preparation of Early-Late Heterobimetallic Complexes.

The cycloheptatrienyl-cyclopentadienyl sandwich complex [η-CH)Ti(η-CH)) (troticene) can be dilithiated (once at each ring) or selectively monolithiated, either at the seven- or five-membered ring, depending on the reaction conditions. Treatment of the resulting lithiotroticenes with CIPPh2 afforded...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 131; no. 46; pp. 17014 - 17024
Main Authors:	Mohapatra, Swagat K., Büschel, Susanne, Daniliuc, Constantin, Jones, Peter G., Tamm, Matthias
Format:	Article
Published:	American Chemical Society 11/25/2009
Subjects:	X-ray diffraction Ferrocene Chemical reactions Metal complexes Molecular structure
Online Access:	View this record in EBSCOhost