Rhodium(0) Metalloradicals in Binuclear C — H Activation.
The article presents a study on the computed minimum-energy reaction pathway mechanism (MERP) for Rhodium metalloradicals. The study executed density functional theory (DFT) calculations to know the nature of the reaction path and rate-limiting step of the metalloradicals. The results manifest that...
| Publicado en: | Journal of the American Chemical Society Vol. 132; no. 1; pp. 73 - 76 |
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| Autores principales: | , , |
| Formato: | Artículo |
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American Chemical Society
1/13/2010
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=48230193&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 48230193 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 1/13/2010 vid: 132 iid: 1 pid: 997 pub: American Chemical Society artinfo: ui: 48230193 10.1021/ja909022p ppf: 73 ppct: 3 formats: tig: atl: Rhodium(0) Metalloradicals in Binuclear C — H Activation. aug: au: Puschmann, Florian F. Grutzmacher, Hansjörg de Bruin, Bas affil: Department of Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands Department of Chemistry and Applied Biology, ETH-Hönggerberg, CH-8093 Zürich, Switzerland su: Rhodium compounds Radicals (Chemistry) Chemical reactions Density functionals Activation (Chemistry) Chemical bonds sug: subj: Rhodium compounds Radicals (Chemistry) Chemical reactions Density functionals Activation (Chemistry) Chemical bonds ab: The article presents a study on the computed minimum-energy reaction pathway mechanism (MERP) for Rhodium metalloradicals. The study executed density functional theory (DFT) calculations to know the nature of the reaction path and rate-limiting step of the metalloradicals. The results manifest that the cooperative action of two Rh radicals could be used in bond activation chemistry and binuclear oxidative addition of its C-H bonds can be used for follow-up reactivity. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2010 holdings: @attributes: islocal: N |
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