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In Situ Single Crystal Diffraction Studies of the Structural Transition of Metal–Organic Framework Copper 5-Sulfoisophthalate, Cu-SIP-3.

The flexibility of the metal-organic framework Cu(OH)(CHOS)(HO)•2HO (Cu-SIP-3) toward reversible single-crystal to single-crystal transformations is demonstrated using in situ diffraction methods at variable temperature. At temperatures below a dehydration-induced phase transition (T < 370 K) the st...

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Published in:Journal of the American Chemical Society Vol. 132; no. 10; pp. 3605 - 3612
Main Authors: Allan, Phoebe K., Bo Xiao, Teat, Simon J., Knight, Jason W., Morris, Russell E.
Format: Article
Published: American Chemical Society 3/17/2010
Subjects:
Optical diffraction
X-ray diffraction
Copper
Bragg gratings
Nitric oxide
X-ray spectroscopy
Online Access:View this record in EBSCOhost