Origins of the Selectivity for Borylation of Primary over Secondary C-H Bonds Catalyzed by Cp -Rhodium Complexes.

Detailed experimental and computational studies of the high selectivity for functionalization of primary over secondary sp C-H bonds in alkanes by borane reagents catalyzed by Cp*Rh complexes are reported. Prior studies have shown that Cp*RhX)(Bpin) (X = H or Bpin), generated from Cp*Rh(H)(Bpin) and...

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Publicado en:	Journal of the American Chemical Society Vol. 132; no. 9; pp. 3078 - 3092
Autores principales:	Wei, Carolyn S., Jiménez-Hoyos, Carlos A., Videa, Marcelo F., Hartwig, John F., Hall, Michael B.
Formato:	Artículo
Publicado:	American Chemical Society 3/10/2010
Materias:	Chemical bonds Alkanes Boranes Complex compounds Density functionals Propane Scission (Chemistry)
Acceso en línea:	Ver este registro en EBSCOhost