Electron Transport Properties of Atomic Carbon Nanowires between Graphene Electrodes.

Long, stable, and free-standing linear atomic carbon wires (carbon chains) have been carved out from graphene recently [Meyer et at. Nature (London) 2008, 454, 319; Jin et at. Phys. Rev. Left. 2009, 102, 205501]. They can be considered as extremely narrow graphene nanoribbons or extremely thin carbo...

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Publicado en:Journal of the American Chemical Society Vol. 132; no. 33; pp. 11481 - 11487
Autores principales: Shen, Lei, Zeng, Minggang, Yang, Shuo-Wang, Zhang, Chun, Wang, Xuefeng, Yuanping Feng
Formato: Artículo
Publicado: American Chemical Society 8/25/2010
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Acceso en línea:Ver este registro en EBSCOhost
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      dt: 8/25/2010
      vid: 132
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      pub: American Chemical Society
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        10.1021/Ja909531c
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        atl: Electron Transport Properties of Atomic Carbon Nanowires between Graphene Electrodes.
      aug:
        au:
          Shen, Lei
          Zeng, Minggang
          Yang, Shuo-Wang
          Zhang, Chun
          Wang, Xuefeng
          Yuanping Feng
        affil:
          Department of Physics, 2 Science Drive 3, National University of Singapore, Singapore 117542, Singapore
          Institute of High Performance Computing, 1 Fusionopolis Way, 16-16 Connexis, Singapore 138632, Singapore
          NanoCore, 5A Engineering Drive 4, National University of Singapore, Singapore 117576, Singapore
          Department of Physics, Soochow University, Suzhou 215006, China
      su:
        Electric wire
        Electron transport
        Graphene
        Carbon electrodes
        Field-effect transistors
        Green's functions
        Density functionals
      sug:
        subj:
          Electric wire
          Electron transport
          Graphene
          Carbon electrodes
          Field-effect transistors
          Green's functions
          Density functionals
      ab: Long, stable, and free-standing linear atomic carbon wires (carbon chains) have been carved out from graphene recently [Meyer et at. Nature (London) 2008, 454, 319; Jin et at. Phys. Rev. Left. 2009, 102, 205501]. They can be considered as extremely narrow graphene nanoribbons or extremely thin carbon nanotubes. It might even be possible to make use of high-strength and identical (without chirality) carbon wires as a transport channel or on-chip interconnects for field-effect transistors. Here we investigate electron transport properties of linear atomic carbon wire-graphene junctions by combining nonequilibrium Green's function with density functional theory. For short wires, linear ballistic transport is observed in wires consisting of odd numbers of carbon atoms but not in those consisting of even numbers of carbon atoms. For wires longer than 2.1 nm as fabricated above, however, the ballistic conductance of carbon wire-graphene junctions is independent of the structural distortion, structural imperfections, and hydrogen impurity adsorbed on the linear carbon wires, except for oxygen impurity adsorption under a low bias. As such, the epoxy groups might be the origin of experimentally observed low conductance in the carbon chain. Moreover, double-atomic carbon chains exhibit a negative differential resistance effect.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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