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Synthesis, Structure, and Density Functional Theory Analysis of a Scandium Dinitrogen Complex, [(CMeH)Sc](μ-η:η-N).

Investigation of the bis(tetramethylcyclopentadienyl) metallocene chemistry of scandium has revealed that the method involving reduction of trivalent salts with alkali metals used with lanthanides can also be applied to scandium to make a dinitrogen complex of the first member of the transition meta...

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Published in:Journal of the American Chemical Society Vol. 132; no. 32; pp. 11151 - 11159
Main Authors: Demir, Selvan, Lorenz, Sara E., Ming Fang, Furche, Filipp, Meyer, Gerd, Ziller, Joseph W., Evans, William J.
Format: Article
Published: American Chemical Society 8/18/2010
Subjects:
Rare earth metal metallurgy
Scandium
Metallocenes
Carbynes
Tetraphenylborates
Anions
Online Access:View this record in EBSCOhost