Mixed Low-Dimensional Nanomaterial: 2D Ultranarrow MoS Inorganic Nanoribbons Encapsulated in Quasi-1D Carbon Nanotubes.

Quasi-one-dimensional nanotubes and two-dimensional nanoribbons are two fundamental forms of nanostructures, and integrating them into a novel mixed low-dimensional nanomaterial is fascinating and challenging. We have synthesized a stable mixed low-dimensional nanomaterial consisting of MoS inorgani...

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Detalles Bibliográficos
Publicado en:Journal of the American Chemical Society Vol. 132; no. 39; pp. 13840 - 13848
Autores principales: Zhiyong Wang, Hong Li, Zheng Liu, Zujin Shi, Jing Lu, Suenaga, Kazu, Soon-Ku Joung, Okazaki, Toshiya, Zhennan Gu, Jing Zhou, Zhengxiang Gao, Guangping Li, Sanvito, Stefano, Enge Wang, Lijima, Sumio
Formato: Artículo
Publicado: American Chemical Society 10/6/2010
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Acceso en línea:Ver este registro en EBSCOhost
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Sumario:Quasi-one-dimensional nanotubes and two-dimensional nanoribbons are two fundamental forms of nanostructures, and integrating them into a novel mixed low-dimensional nanomaterial is fascinating and challenging. We have synthesized a stable mixed low-dimensional nanomaterial consisting of MoS inorganic nanoribbons encapsulated in carbon nanotubes (which we call nanoburritos). This route can be extended to the synthesis of nanoburritos composed of other ultranarrow transition-metal chalcogenide nanoribbons and carbon nanotubes. The widths of previously synthesized MoS ribbons are greater than 50 nm, while the encapsulated MoS nanoribbons have uniform widths down to 1-4 nm and layer numbers down to 1-3, depending on the nanotube diameter. The edges of the MoS nanoribbons have been identified as zigzag-shaped using both high-resolution transmission electron microscopy and density functional theory calculations.