Cover Image
QR Code

Water-Soluble J-Type Rosette Nanotubes with Giant Molar Ellipticity.

A new self-assembling tricyclic module (×K1) featuring the Watson-Crick H-bonding arrays of guanine and cytosine fused to an internal pyridine ring was synthesized. When dissolved in water at room temperature, this module rapidly self-assembles into hexameric rosettes, which then stack to form J-typ...

Full description

Published in:Journal of the American Chemical Society Vol. 132; no. 43; pp. 15136 - 15140
Main Authors: Borzsonyi, Gabor, Beingessner, Rachel L., Yamazaki, Takeshi, Jae-Young Cho, Myles, Andrew J., Malac, Marek, Egerton, Ray, Kawasaki, Masahiro, Ishizuka, Kazuo, Kovalenko, Andriy, Fenniri, Hicham
Format: Article
Published: American Chemical Society 11/3/2010
Subjects:
Nanotubes
Quadruplex nucleic acids
Pyridine nucleotides
Electronic systems
Fullerenes
Imaging systems
Online Access:View this record in EBSCOhost
fields @attributes:
  recordID: 1
pdfLink:
plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=55093119&site=ehost-live
header:
  @attributes:
    shortDbName: hlh
    uiTerm: 55093119
    longDbName: Humanities International Complete
    uiTag: AN
  controlInfo:
    bkinfo:
    jinfo:
      jid:
        00027863
        ACS
      jtl: Journal of the American Chemical Society
      issn: 00027863
      maglogo: N
    pubinfo:
      dt: 11/3/2010
      vid: 132
      iid: 43
      pid: 997
      pub: American Chemical Society
    artinfo:
      ui:
        55093119
        10.1021/ja105028w
      ppf: 15136
      ppct: 4
      formats:
      tig:
        atl: Water-Soluble J-Type Rosette Nanotubes with Giant Molar Ellipticity.
      aug:
        au:
          Borzsonyi, Gabor
          Beingessner, Rachel L.
          Yamazaki, Takeshi
          Jae-Young Cho
          Myles, Andrew J.
          Malac, Marek
          Egerton, Ray
          Kawasaki, Masahiro
          Ishizuka, Kazuo
          Kovalenko, Andriy
          Fenniri, Hicham
        affil:
          National Institute for Nanotechnology, University of Alberta, 11421 Saskatchewan Drive, Edmonton, Alberta, T6G 2M9, Canada
          Department of Chemistry, University of Alberta, 11421 Saskatchewan Drive, Edmonton, Alberta, T6G 2M9, Canada
          Department of Physics, University of Alberta, 11421 Saskatchewan Drive, Edmonton, Alberta, T6G 2M9, Canada
          JEOL USA, Inc., 11 Dearborn Road, Peabody, Massachusetts 01960
          HREM Research, 14-48 Matsukazedai, Higashimastuyama, 355-0055, Japan
          Department of Mechanical Engineering, University of Alberta, 11421 Saskatchewan Drive, Edmonton, Alberta, T6G 2M9, Canada
      su:
        Nanotubes
        Quadruplex nucleic acids
        Pyridine nucleotides
        Electronic systems
        Fullerenes
        Imaging systems
      sug:
        subj:
          Nanotubes
          Quadruplex nucleic acids
          Pyridine nucleotides
          Electronic systems
          Fullerenes
          Imaging systems
      ab: A new self-assembling tricyclic module (×K1) featuring the Watson-Crick H-bonding arrays of guanine and cytosine fused to an internal pyridine ring was synthesized. When dissolved in water at room temperature, this module rapidly self-assembles into hexameric rosettes, which then stack to form J-type rosette nanotubes (RNTs) with increased inner/outer diameters and the largest molar ellipticity ever reported (4 × 10 deg·M·m). Using a combination of imaging and spectroscopic techniques we established the structure of ×K1-RNT and have shown that the extended π system of the self-assembling module resulted in a new family of J-type RNTs with enhanced intermodular electronic communication.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
    refInfo:
    copyright:
      @attributes:
        flag: Y
      dt:
        @attributes:
          year: 2010
    holdings:
      @attributes:
        islocal: N